MIPs logo MIPdatabase      MIP2020 Conference logo Use this space
Custom Search
Reference type: Journal
Authors: Mukawa T, Goto T, Nariai H, Aoki Y, Imamura A, Takeuchi T
Article Title: Novel strategy for molecular imprinting of phenolic compounds utilizing disulfide templates.
Publication date: 2003
Journal: Journal of Pharmaceutical and Biomedical Analysis
Volume: 30
Issue: (6)
Page numbers: 1943-1947.
DOI: 10.1016/S0731-7085(02)00538-1

Abstract: A molecularly imprinted polymer was synthesized by using allyl phenyl disulfide as a template. The mixture of allyl phenyl disulfide, divinylbenzene, and 2,2'-azobis(isobutyronitrile) in chloroform was polymerized by UV irradiation for 24 h at 5 degreesC and further 3 h at 80 degreesC. The disulfide bonds of the resulting polymer were reductively cleaved by NaBH4 in methanol to give thiol groups in the binding sites. The polymer selectively recognized phenol rather than thiophenol. In chromatographic study using polymer-packed columns, the retention factor of the IP for phenol was 5.60 and that of a reference polymer was 4.20. The higher retention for phenol was supported by ab initio calculation. (C) 2002 Elsevier Science B.V. All rights reserved

  mipdatabase.com logo imprinters do it in bulk shirt  Science Teacher peptide mug  Perpetual student shirt

Molecules Special Issue call      Appeal for information


Join the Society for Molecular Imprinting
Logo of the Society for Molecular Imprinting

New items RSS feed
new items RSS feed  View latest updates

Sign-up for e-mail updates:
Choose between receiving an occasional newsletter or more frequent e-mail alerts.
Click here to go to the sign-up page.

Is your name elemental or peptidic? Enter your name and find out by clicking either of the buttons below!
Other products you may like:
view listings for MIP books on eBay:

Mickey Mouse 90th Anniversary banner