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Reference type: Journal
Authors: Nishide H, Deguchi J, Tsuchida E
Article Title: Adsorption of metal ions on crosslinked poly(4-vinylpyridine) resins prepared with a metal ion as template.
Publication date: 1977
Journal: Journal of Polymer Science, Polymer Chemistry Edition
Volume: 15
Issue: (12)
Page numbers: 3023-3029.
DOI: 10.1002/pol.1977.170151216

Abstract: Poly(4-vinylpyridine) (PVP) was crosslinked with 1,4-dibromobutane with a metal ion as template. The adsorption behavior of copper, cobalt, zinc, and cadmium ions on the obtained resin (DBQP) was studied. The DBQP resin prepared with a metal ion as template preferentially adsorbed the metal ion used as template. The stability constant of the copper complex of DBQP was largest for the DBQP resin prepared with a copper ion as template, which was due to its large entropy change for the complexation.


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