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Reference type: Journal
Authors: He FF, Wang HQ, Wang YY, Wang F, Zhang HS, Li HL, Tang JH
Article Title: Magnetic Th(IV)-ion imprinted polymers with salophen schiff base for separation and recognition of Th(IV).
Publication date: 2013
Journal: Journal of Radioanalytical and Nuclear Chemistry
Volume: 295
Issue: (1)
Page numbers: 167-177.
DOI: 10.1007/s10967-012-1891-y

Abstract: A new complex of N , N '-bis(3-allyl salicylidene) o -phenylenediamine and thorium(IV) (Th(IV)) was synthesized and used as the functional monomer for a novel Th(IV) magnetic ion-imprinted polymer; this polymer was synthesized using a surface imprinting technique that included the modified magnetic Fe 3 O 4 particle and used tetraethyl orthosilicate, 3-Aminopropyltriethoxysilane and maleic anhydride in the process. The magnetic polymer was characterized using FT-IR, and powder- and single crystal-XRD. The behavior of Th(IV) was investigated using batch experiments. At pH 4.5, the uptake capacity of this adsorbent and that of the non-imprinted polymer was 42.54 and 14.10 mg g -1 , respectively, and the relative selectivity coefficient values of the synthesized adsorbent for Th(IV)/La(III), Th(IV)/Ce(III), Th(IV)/Nd(III), and Th(IV)/U(VI) were 82.2, 93.1, 21.0 and 62.4 times greater than that of the non-imprinted matrix, respectively. In addition, the Th(IV) adsorption process using Fe 3 O 4 @SiO 2 -IIP follows pseudo-second-order reaction kinetics and the Langmuir adsorption isotherm. The thermodynamic parameters also suggest that the adsorption of Th(IV) onto Fe 3 O 4 @SiO 2 -IIPs was a spontaneous and endothermic process
Template and target information: thorium ion, Th(IV)
Author keywords: Magnetic absorbent, Thorium ion, imprinted polymers, Schiff base, separation

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