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Reference type: Journal
Authors: Reddy PS, Kobayashi T, Fujii N
Article Title: Recognition characteristics of dibenzofuran by molecularly imprinted polymers made of common polymers.
Publication date: 2002
Journal: European Polymer Journal
Volume: 38
Issue: (4)
Page numbers: 779-785.
DOI: 10.1016/S0014-3057(01)00231-2

Abstract: Dibenzofuran (DBF) recognition was studied by a molecularly imprinted polymer (MIP) made of commercially available polymers: polyvinyl chloride (PVC), polysulfone, polystyrene. and polyacrylonitrile. Preparation of MIPs was carried out by phase inversion of the polymer. Respective Polymer solutions were coagulated with DBF template in water (non-solvent). In addition. reference polymers without the template were prepared in same manner as unimprinted polymers. After the DBF template was extracted from the solidified polymers by washing with methanol (MeOH). recognition experiments of DBF by the imprinted polymers were carried out for DBF in MeOH solutions. Equilibrium constants for DBF were calculated from saturation binding kinetics. Equilibrium experiment results reveal that recognition was effective for DBF binding to the DBF-imprinted polymer, especially for the imprinted PVC. (C) 2002 Elsevier Science Ltd. All rights reserved


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