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Reference type: Journal
Authors: Lin ZZ, Wu QS, Zhang HY, Lin YD, Huang ZY
Article Title: Preparation and Adsorption Ability of Molecularly Imprinted Polymer Microspheres for Malachite Green.
Publication date: 2013
Journal: International Journal of Polymer Analysis and Characterization
Volume: 18
Issue: (8)
Page numbers: 578-586.
DOI: 10.1080/1023666X.2014.837214

Abstract: Molecularly imprinted polymer (MIP) microspheres were synthesized through precipitation polymerization using malachite green (MG) as template, methacrylic acid (MAA) as monomer, and trimethylolpropane trimethacrylate (TRIM) as cross-linker. The microsphere structure of MIP was characterized by IR spectroscopy and SEM. The influence of preparation conditions such as monomer and cross-linker dosages on the polymer absorption of MG in acetonitrile solution was also explored. Under the optimum synthesis conditions (0.25 mmol MG, 1.5 mmol MAA, 2.5 mmol TRIM, 40 mL acetonitrile), the prepared MIP microspheres have a binding capacity as high as 2000 μg g-1 of MG with an imprinting factor of above 4.0. The result suggests that the prepared MIP microspheres are promising material for the selective extraction of MG in complicated matrix solutions
Template and target information: malachite green, MG
Author keywords: adsorption, Malachite green, molecular recognition, molecularly imprinted polymer, precipitation polymerization

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