MIPdatabase
Authors: Wang L, Xu ZB, Wang P, Xue M, Dong XM, Meng ZH, Lou ZL, Lin ZH, Lu CY
Article Title: Selective Extraction of N-Heterocyclic Precursors of 1,3,5,7-Tetranitro-1,3,5,7-tetraazacyclooctane (HMX) Using Molecularly Imprinted Polymers.
Publication date: 2013
Journal: Propellants, Explosives, Pyrotechnics
Volume: 38
Issue: (6)
Page numbers: 781-785.
DOI: 10.1002/prep.201300016
Abstract: N-heterocyclic compounds are key nitration precursors for some high energy density explosives such as 1,3,5,7-tetranitro-1,3,5,7-tetraazacyclooctane (HMX). Nitration of 1,3,5,7-tetraacetyl-1,3,5,7-tetraazacyclooctane (TAT) yields HMX in high yields and purity. However, the analogue 1,3,5-triacetyl-1,3,5-triazacyclohexane (TRAT) is easily co-produced via the condensation of acetonitrile and 1,3,5-trioxan. To selectively extract TAT from a mixture of TAT and TRAT, the molecular imprinting technology (MIT) was developed in this study. The capacity of the dry polymer is 16 mg g-1 and the recovery surpasses 75 %
Template and target information: 1,3,5,7-tetraacetyl-1,3,5,7-tetraazacyclooctane, TAT
Author keywords: 1,3,5,7-Tetraacetyl-1,3,5,7-tetraazacyclooctane, 1,3,5-Triacetyl-1,3,5-triazacyclohexan, Molecularly imprinted polymers, solid phase extraction, frontal chromatography
Join the Society for Molecular Imprinting
New items RSS feed
View latest updatesSign-up for e-mail updates:
Choose between receiving an occasional newsletter or more frequent e-mail alerts.
Click here to go to the sign-up page.
Is your name elemental or peptidic? Enter your name and find out by clicking either of the buttons below!
