Authors: Santora BP
, Larsen AO
, Gagné MR
Toward the molecular imprinting of titanium Lewis acids: Demonstration of Diels-Alder catalysis.
Publication date: 1998
Abstract: This communication reports the free radical incorporation of a titanium(IV) complex containing polymerizable aryloxide ligands into a rigid and porous polystyrene/divinylbenzene-based matrix. This yields a yellow-orange insoluble polymer that can, be converted into a dark red polymer with SiCl4; the latter polymer is a good catalyst for the Diets-Alder reaction
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