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Reference type: Journal
Authors: Wolska J, Kujawska M, Cyganowski P
Article Title: Ph-Responsive Molecularly Imprinted Polymer for Sorption and Rapid Desorption of Dibutyl Phthalate.
Publication date: 2017
Journal: Separation Science and Technology
Page numbers: null.
DOI: 10.1080/01496395.2017.1310235

Abstract: The pH-responsive molecularly imprinted polymers (SR-MIPs) for the removal of dibutyl phthalate (DBP) were obtained. The polymers were synthesized using methyl methacrylate, methacrylic acid, divinylbenzene and a template mixed at different ratios allowing to optimize the process. The so-prepared SR-MIPs were evaluated at various pH in processes of DBP sorption. The studies covered evaluation of uptake capacity, sorption kinetics, selectivity and elution. The imprinted samples are characterized by improved factors comparing to their non-imprinted analogues, revealing also pH-sensitivity. The highest removal of DBP (130 mg g-1) was achieved at pH=6, while pH-driven desorption (90%) was the most efficient at pH=8
Author keywords: Dibutyl phthalate, pH-responsive molecularly imprinted polymers, sorption, Desorption, selectivity

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