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Reference type: Journal
Authors: Kueseng P, Nisoa M, Sontimuang C
Article Title: Rapid preparation of molecularly imprinted polymers by custom-made microwave heating for analysis of atrazine in water.
Publication date: 2018
Journal: Journal of Separation Science
DOI: 10.1002/jssc.201800198

Abstract: The rapid preparation of an atrazine-imprinted polymer in a cost-effective custom-made microwave reactor was demonstrated. The polymerization reaction was accelerated by microwave heating, and the preparation time was greatly shortened (to 1 h). The resulting polymer was successfully applied as solid-phase extraction adsorbent for the selective extraction and preconcentration of atrazine in environmental water samples. The binding capacity of the polymer was 1.11 mg/g polymer. The polymer provided selectivity with higher recovery of atrazine than of other interfering related contaminants. The proposed method had good limits of detection and quantitation at 0.20 and 0.60 ng/mL, respectively. The recoveries were from 83 to 89% at two spiking levels, with relative standard deviations less than 5%. This method was successfully applied to determine the atrazine levels in environmental water samples. This article is protected by copyright. All rights reserved
Author keywords: Atrazine, high-performance liquid chromatography, Microwave heating, Molecularly imprinted polymer, Solid-phase extraction


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