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Reference type: Journal
Authors: Mandler D, Shahar T, Feldheim G, Marx S
Article Title: Core-shell nanoparticles for gas phase detection based on silver nanospheres coated with a thin molecularly imprinted polymer adsorbed on a chemiresistor.
Publication date: 2018
Journal: Nanoscale
DOI: 10.1039/C8NR01437J

Abstract: We present a novel gas phase detection prototype based on assembling core-shell nanospheres made of silver core and coated with a molecularly imprinted polymer (MIP) adsorbed onto an interdigitated array (IDA) electrode chemiresistor (CR). The core-shell nanospheres, AgNP@MIPs, were imprinted with linalool, a volatile terpene alcohol, as a model system. The thickness of the MIP layer was tuned to a few nanometer to enable the facile ingress and egress of the linalool, as well as to enhance the electrical transduction through the Ag core. The AgNP@MIPs were spread onto the IDA-CR modified with various positively charged polymers, by drop casting and dip-coating. The AgNP@MIPs were characterized by XHR-SEM and XHR-STEM, FTIR, EDX and XRD. The MIP recognition event was transduced into a measurable increase in the resistance. The response to linalool exposure and removal was fast and the device was fully recovered and could be reused. Finally, the dif-ference in the resistance change between imprinted and non-imprinted nanospheres was substantial


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