Abstract: Surface molecularly imprinted polymer named Fe3O4@ZIF-8@MIP is synthesized and applied in selective adsorption of tetrabrombisphenol A (TBBPA) in water. Core-shell magnetic metal-organic framework (MMOF) structure is chosen as the substrate and imprinted layer is then covered on its surface. Thus, the adsorbent combines both large specific surface area and abundant pores supplied by MMOF with specific recognition sites from imprinted technology together, acquiring better adsorption effect in adsorption of TBBPA and its structural analogues. More importantly, contributed by the magnetic core, the material is separated and reused conveniently, which is beneficial for actual application. The adsorption properties of nanospheres are evaluated through the extraction of TBBPA in sample and the maximum adsorption capacity can reach 117.6 mg g-1 in 15 min satisfactorily