Reference type: Journal
Authors: Matsuishi T,
Shimada T,
Morihara K
Article Title: Footprint catalysis 9. Molecular footprint catalytic cavities imprinted with chiral hydantoins - enantioselective hydantoinase mimics.
Publication date: 1994
Journal: Bulletin of the Chemical Society of Japan
Volume: 67
Issue: (3)
Page numbers: 748-756.
DOI: 10.1246/bcsj.67.748
Abstract: Imprinting using chiral 5-phenyhydantoins ((5R)- and (5S)-5-pheny- 2,4-imidazolinedione) as templates could mark chiral molecular footprint-like cavities on a silica (alumina) gel surface. These cavities displayed evident enantioselective catalyses in reactions of (R)- and (S)-N-carboxyphenylglycine anhydrides, and (R)- and (S)-5- phenylhydantoins with 2,4-dinitrophenolate, respectively. A proposed mechanism and temperature effects on catalysis suggested that the enantioselectivities depended on the binding step of the catalysis
Join the Society for Molecular Imprinting
New items RSS feed
View latest updates
Sign-up for e-mail updates:
Choose between receiving an occasional newsletter or more frequent
e-mail alerts.
Click
here to go to the sign-up page.
Is your name
elemental or
peptidic? Enter your name and find out by clicking either of the buttons below!
Other products you may like:
view listings for MIP books on eBay: