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Reference type: Journal
Authors: Tan J, Li R, Jiang ZT
Article Title: Discrimination of fresh fruit juices by a fluorescent sensor array for carboxylic acids based on molecularly imprinted titania.
Publication date: 2014
Journal: Food Chemistry
Volume: 165
Page numbers: 35-41.
DOI: 10.1016/j.foodchem.2014.05.104
Alternative URL: http://www.sciencedirect.com/science/article/pii/S0308814614008206

Abstract: Design of chemical sensor arrays that can discriminate real-world samples has been highly attractive in recent years. Herein a fluorescent indicator-displacement sensor array for discrimination of fresh fruit juices was developed. By coupling the unique high affinity of titania to electron-donating anions and the cross-reactivity of molecularly imprinted materials to structurally similar species, a small array was fabricated using only one rhodamine-based fluorescent dye and three synthesized materials. Citric, malic, succinic and tartaric acids were chosen as indices. The recognition mechanism was investigated by spectrofluorimetric titration using a non-linear Langmuir-type adsorption model. The proposed method was applied to discriminate thirteen fruit juices through their carboxylic acid contents. Principal component analysis of the data clearly grouped the thirteen juices with the first principal component owning 98.2% of the total variation. The comparison of the sensor array with HPLC determination of the carboxylic acids was finally made
Template and target information: citric acid, malic acid, succinic acid, tartaric acid
Author keywords: Sensor array, molecular imprinting, titania, Fluorescent indicator-displacement, Carboxylic acid, Fresh fruit juice


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