Authors: Terashima T
, Kojima H
, Sawamoto M
Core-imprinted Star Polymers via Living Radical Polymerization: Precision Cavity Microgels for Selective Molecular Recognition.
Publication date: 2014
Journal: Chemistry Letters
Alternative URL: https://www.jstage.jst.go.jp/article/cl/43/11/43_140605/_article
Abstract: Core-imprinted star polymers with precision cavity microgels were designed by living radical polymerization with molecular imprinting for selective molecular recognition. The key is to employ NaI-bearing poly(ethylene glycol) dimethacrylate as a template linker during the linking process of poly(methyl methacrylate) arms with ethylene glycol dimethacrylate; Na-imprinted PEG loop cavities are thus effectively created within microgels. As a result, the star polymer encapsulated NaI 15 times more selectively than KI under competitive conditions
Template and target information: sodium ion, Na(I), NaI
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