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Reference type: Journal
Authors: Tarbin JA, Sharman M
Article Title: Synthesis and preliminary evaluation of a molecularly imprinted polymer selective for artificial phenolic estrogenic compounds.
Publication date: 1999
Journal: Analytical Communications
Volume: 36
Issue: (3)
Page numbers: 105-107.
DOI: 10.1039/a900197b

Abstract: A molecularly imprinted polymer has been prepared using a hexestrol template. The polymer was synthesised using diethylaminoethyl methacrylate (DAEM) as functional monomer and trimethylolpropane trimethacrylate as crosslinking monomer via a photoinitiated addition polymerisation. An equivalent blank polymer was also synthesised in the absence of the template compound. After packing into a stainless steel column (150 x 4.6 mm id), retention and elution of the template and related compounds were evaluated by high-performance liquid chromatography (HPLC). The results showed that the material synthesised in the presence of hexestrol demonstrated a selectivity towards compounds containing the stilbene carbon backbone (diethylstilbestrol, dienestrol, hexestrol)


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