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Reference type: Journal
Authors: Whitcombe MJ, Martin L, Vulfson EN
Article Title: Predicting the selectivity of imprinted polymers.
Publication date: 1998
Journal: Chromatographia
Volume: 47
Issue: (7-8)
Page numbers: 457-464.
DOI: 10.1007/BF02466481

Abstract: Imprinted polymers as stationary phases for HPLC separations have been the subject of extensive investigations in recent years. In order to aid the rational design of synthetic protocols for the preparation of imprinted polymers, a series of calculations were made to assess the equilibrium concentration of template-monomer complexes as a function of association constant (K) for the functional groups involved in the interactions and initial concentrations of reactants. This data was then used to predict the selectivity of polymers prepared under different reaction conditions and the model was tested using an experimentally determined value of K and separation factors taken from the literature

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