Authors: Patel A
, Fouace S
, Steinke JHG
Novel stereoselective molecularly imprinted polymers via ring-opening metathesis polymerisation.
Publication date: 2004
Journal: Analytica Chimica Acta
Abstract: Stereoselective molecularly imprinted polymers (MIPs) have been synthesised via ring-opening metathesis polymerisation, in essentially, quantitative yield. A covalent imprinting strategy was followed during the network formation of the chiral sorbent. Recognition of the substrate however involved non- covalent interactions; a combination of hydrogen bonding and the chiral environment presented by the imprinted cavities. The enantiomeric excess achievable with these new MIPs is solvent dependent and stereoselectivities of up to 20% e.e. (separation factor alpha = 2.2) were found in batch equilibrations. (C) 2003 Elsevier B.V. All rights reserved
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