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Reference type: Journal
Authors: Efendiev AA
Article Title: Macromolecular metal complexes with memory to the catalyzed substrate.
Publication date: 1998
Journal: Macromolecular Symposia
Volume: 131
Issue: (1)
Page numbers: 29-38.
DOI: 10.1002/masy.19981310106

Abstract: A number of complexing polymers containing carboxylic, phosphorylic, amine, imine and pyridine functional groups have been prepared and their complexes with copper, cobalt and nickel have been obtained. The complexes were prearranged for reactions of liquid phase oxidation and hydrogenation of hydrocarbons by means of formation and subsequent fixation in memory of the catalysts the structure of active centres favorable for catalyzed substrate. It has been shown that the prearranged complexes might "remember" the structure optimum for the substrate and this leads to an essential increase in catalytic activity and selectivity of the catalysts
Template and target information: copper ion, cobalt ion, nickel ion


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