Authors: Yoshikawa M
, Yonetani K
, Koso K
, Kitamura S
, Kimura S
Publication date: 2002
Chiral recognition ability of molecularly imprinted membranes with oligopeptide derivative tweezers.
Alternative URL: http://www.jstage.jst.go.jp/article/spsjppj/51/0/51_331/_article
Proceedings title: Polymer Preprints, Japan
Volume number: 51
Abstract: Novel molecularly imprinted polymeric membranes were prepared from oligopeptide derivative tweezers, of which number of constituting amino acid residue was three. The membranes were prepared by using Boc-D-Trp as a print molecule. The D-isomer, Ac-D-Trp, was always incorporated in the membrane in preference to the corresponding L-isomer. The affinity constant between chiral recognition site and Ac-D-Trp was determined to be 1.05×104 mol-1dm3.
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