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Reference type: Journal
Authors: Marty JD, Mauzac M, Gornitzka H
Article Title: Chiral molecular imprinting in liquid-crystalline network.
Publication date: 2005
Journal: European Physical Journal E
Volume: 17
Issue: (4)
Page numbers: 515-520.
DOI: 10.1140/epje/i2004-10156-3

Abstract: A cholesteric imprinted elastomer was obtained by cross-linking a nematic side-chain polysiloxane around a chiral template. The template was first linked to some functionalised groups of the polymer via hydrogen-bound interactions, then was removed by washing. The sample was macroscopically oriented during the synthesis; so, both a molecular chirality and a supramolecular phase chirality were topologically imprinted inside the network. Batch rebinding experiments, performed in the presence of the template or of the other enantiomer, showed that the imprinted polymer has a pronounced stereo-selectivity towards the template enantiomer. The rebinding capacity appeared to be greater than an unimprinted mesogenic network as well as than an imprinted non mesogenic one. EDP Sciences / Societa Italiana di Fisica / Springer-Verlag 2005
Template and target information: N-(carbobenzyloxy)-L-phenylalanine

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