Authors: Takeuchi T
, Minato Y
, Takase M
, Shinmori H
Molecularly imprinted polymers with halogen bonding-based molecular recognition sites.
Publication date: 2005
Journal: Tetrahedron Letters
Abstract: Molecular recognition materials bearing halogen bonding-based binding sites were synthesized by a non-covalent imprinting technique using a 2,3,5,6-tetrafluoro-4-iodostyrene (TFIS) as the functional monomer. The binding sites were generated by co-polymerizing TFIS, styrene and divinylbenzene in the presence of the template molecule (4-dimethylaminopyridine--DMAP). The imprinted polymer preferentially adsorbed aminopyridine derivatives, suggesting that halogen bonding may play a role in the selective recognition of analytes by the synthesized synthetic receptor
Template and target information: 4-dimethylaminopyridine, DMAP
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