MIPdatabase
Authors: Ou JJ, Hu LH, Hu LG, Li X, Zou HF
Article Title: Determination of phenolic compounds in river water with on-line coupling bisphenol A imprinted monolithic precolumn with high performance liquid chromatography.
Publication date: 2006
Journal: Talanta
Volume: 69
Issue: (4)
Page numbers: 1001-1006.
DOI: 10.1016/j.talanta.2005.12.003
Alternative URL: http://www.sciencedirect.com/science/article/B6THP-4J021GS-8/2/ac1299a581683168bf02cd700ce7b1d2
Abstract: The bisphenol A (BPA) imprinted monolithic precolumn has been prepared by in situ polymerization using 4-vinylpyridine (4-VP) and ethylene dimethacrylate (EDMA) as functional monomer and cross-linker, respectively. The column with good flow-through property was obtained by changing the molar ratio of the porogens (toluene and dodecanol). The selectivity and retention properties of the monolith for the BPA and other phenolic compounds were evaluated. The results show that the hydrophobic and hydrogen-bonding interaction plays important roles in the recognition process. The determination of BPA and other phenolic compounds with on-line solid-phase extraction (SPE) by monolithic precolumn coupled with conventional particulates packed and monolithic reversed-phase columns, respectively, was performed. The method was successfully applied to the analysis of phenolic compounds in river water
Template and target information: bisphenol A, BPA
Author keywords: molecularly imprinted polymer, Monolithic precolumn, bisphenol A, Phenolic compound, On-line solid-phase extraction, column switching
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