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Reference type: Journal
Authors: Hu YL, Wang YY, Chen XG, Hu YF, Li GK
Article Title: A novel molecularly imprinted solid-phase microextraction fiber coupled with high performance liquid chromatography for analysis of trace estrogens in fishery samples.
Publication date: 2010
Journal: Talanta
Volume: 80
Issue: (5)
Page numbers: 2099-2105.
DOI: 10.1016/j.talanta.2009.11.015
Alternative URL: http://ichemical.w1.qiantangren.com/upload/201108312002182468.pdf

Abstract: The combination of molecular imprinting and solid-phase microextraction (SPME) technique provides a powerful sample preparation tool in terms of selectivity, simplicity, and flexibility. This paper reports a novel molecularly imprinted polymer (MIP) coated SPME fiber with 17β-estradiol as template by improved multiple co-polymerization method. The obtained fiber exhibits excellent characteristics such as high porosity, good thermal and chemical stability. Extraction performance shows that the MIP-coated fiber has stronger affinity to the template molecule as compared with the commercial SPME fibers and the control polymer-coated fiber without addition of template. Owing to the shape and structural compatibility, the obtained fiber also demonstrated specific selectivity to the structural related compounds of 17β-estradiol, such as estriol, estrone and 17α-ethynylestradiol, and thus can be applied to simultaneous determination of these estrogens from complex samples coupled with high performance liquid chromatography. The variables that influence extraction were investigated. The MIP-coated fiber demonstrated its efficiency for extraction of estrogens in fishery samples. The detection limits were in the range of 0.98-2.39 μg L-1, and the recoveries were 80.0-83.6% and 85.0-94.1% for fish and shrimp tissue samples, respectively
Template and target information: 17β-estradiol
Author keywords: molecularly imprinted, solid-phase microextraction, estrogens, Fishery sample


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