Authors: Striegler S
, Barnett JD
, Dunaway NA
Glycoside Hydrolysis with Sugar-Templated Microgel Catalysts.
Publication date: 2011
Journal: ACS Catalysis
Abstract: Water-soluble, carbohydrate-templated microgels are explored as catalysts for the hydrolysis of glycosidic bonds. The reaction is more than 2 orders of magnitude accelerated for templated macromolecular catalysts over low-molecular-weight complexes. The structure of the carbohydrate used as template during material preparation directs the catalytic performance of the catalysts to differentiate epimeric substrates.
Template and target information: glycosides
Author keywords: catalysis, hydrolysis, microgel, binuclear copper complex, carbohydrate
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