Authors: Matsuishi T
, Shimada T
, Morihara K
Definitive evidence for enantioselective catalysis over molecular footprint catalytic cavities chirally imprinted on a silica(alumina) gel surface.
Publication date: 1992
Journal: Chemistry Letters
Abstract: "Molecular footprint"-like catalytic cavities were marked on a silica(alumina) gel surface by the authors' molecular imprinting method using a chiral mandelic acid derivative ((-)-(5R)-5-phenyl- 2,4-diketo-tetrahydro-oxazole); these chirally imprinted cavities displayed distinct enantioselective catalysis on the transacylation of the corresponding substrates, N-carboxy-(R)-phenylglycine anhydrides and the (S)-isomer
Template and target information: (-)-(5R)-5-phenyl- 2,4-diketo-tetrahydro-oxazole
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