MIPs logo MIPdatabase      MIP2020 Conference logo Use this space
Custom Search
Reference type: Journal
Authors: Tobiasz A, Walas S, Landowska L, Konefal-Góral J
Article Title: Improvement of copper FAAS determination conditions via preconcentration procedure with the use of salicylaldoxime complex trapped in polymer matrix.
Publication date: 2012
Journal: Talanta
Volume: 96
Page numbers: 82-88.
DOI: 10.1016/j.talanta.2012.02.005
Alternative URL: http://www.sciencedirect.com/science/article/pii/S0039914012001130

Abstract: The paper presents application of a new resin dedicated to copper(II) flow-injection on-line preconcentration prior its flame atomic absorption spectrometric (FAAS) determination. The new sorbent, obtained by suspension polymerization technique, was styrene-divinylbenzene copolymer modified with 5-dodecylsalicylaldoxime-copper(II) complex. In flow mode leaching of initially imprinted Cu(II) ions from polymer beads was effective with 1% (v/v) nitric acid, however for elution of ions retained on the sorbent during the loading process sufficient efficiency was obtained for 0.5% (v/v) nitric acid. The most effective copper(II) sorption was observed within sample pH ca. 6.3 at flow rate 7.5 mL min-1. Furthermore, preconcentration studies of Cu(II) ions realized in the presence of popular foreign ions like Cd(II), Pb(II), Zn(II), Ni(II), Mn(II), Co(II) did not reveal significant interference. The expected effect of Cu(II)-imprinting was confirmed by higher tolerance level for interferents ions concentration for the new sorbent than for the control polymer. It was found that alkaline metals ions and humic acid had the most relevant influence on copper(II) uptake. Accuracy of the evaluated method was assessed for analysis of water samples (tap and mineral water, river water, artesian water) and certified water reference materials compare them to results obtained by inductively plasma mass spectrometry. The satisfactory relative error values obtained with use of standard addition calibration method, confirms the feasibility of this method for Cu(II) determination in water samples. Application of 120 s sorption time enabled to obtain 74-fold enrichment factor and limit of detection (3σ) equal to 0.4 μg L-1
Template and target information: copper ion, Cu(II)
Author keywords: Hydrooxime, preconcentration, ion imprinted polymer, copper determination, FI-FAAS, LIX 622®


  Periodic table Prof shirt  MIPs peptide mug    mug featuring the element Copper

Molecules Special Issue call      Appeal for information






 

Join the Society for Molecular Imprinting
Logo of the Society for Molecular Imprinting

New items RSS feed
new items RSS feed  View latest updates

Sign-up for e-mail updates:
Choose between receiving an occasional newsletter or more frequent e-mail alerts.
Click here to go to the sign-up page.


Is your name elemental or peptidic? Enter your name and find out by clicking either of the buttons below!
Other products you may like:
view listings for MIP books on eBay:



Mickey Mouse 90th Anniversary banner