MIPs logo MIPdatabase      MIP2020 Conference logo Use this space
Custom Search
Reference type: Journal
Authors: Adbo K, Nicholls IA
Article Title: Enantioselective solid-phase extraction using Tröger's base molecularly imprinted polymers.
Publication date: 2001
Journal: Analytica Chimica Acta
Volume: 435
Issue: (1)
Page numbers: 115-120.
DOI: 10.1016/S0003-2670(01)00913-8

Abstract: Molecularly imprinted polymers (MIPs) selective for Troger's base were designed and synthesised, and HPLC-chromatographic evaluation of polymer recognition characteristics was undertaken. Baseline separation of racemic Troger's base was readily achieved, and enantioseparation factors (alpha) of up to 4.8 +/- 0.2 were obtained. The high enantioselectivity demonstrated by these materials prompted their use to examine the kinetics and thermodynamics of individual enantiomers in a solid-phase extraction (SPE) process. Enantiomer-dependent differences in the rates and extent of adsorption were observed. Furthermore, the enantiomeric enrichment of racemates was demonstrated in batch studies. (C) 2001 Elsevier Science B.V. All rights reserved
Template and target information: Tröger's base, Troger's base, 2,8-dimethyl-6H,12H-5,11-methanodibenzo[b, f ][1,5]diazocine


  Magnet featuring the name Karina spelled out in symbols of the chemical elements  Mug featuring the name Karina spelled out in the single letter amino acid code  Man of proper-tea mug in red

Molecules Special Issue call      Appeal for information






 

Join the Society for Molecular Imprinting
Logo of the Society for Molecular Imprinting

New items RSS feed
new items RSS feed  View latest updates

Sign-up for e-mail updates:
Choose between receiving an occasional newsletter or more frequent e-mail alerts.
Click here to go to the sign-up page.


Is your name elemental or peptidic? Enter your name and find out by clicking either of the buttons below!
Other products you may like:
view listings for MIP books on eBay:



Mickey Mouse 90th Anniversary banner