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Reference type: Journal
Authors: Duan YY, Che SN
Article Title: Electron Transition-Based Optical Activity (ETOA) of Achiral Metal Oxides Derived from Chiral Mesoporous Silica.
Publication date: 2013
Journal: Chemistry - A European Journal
Volume: 19
Issue: (32)
Page numbers: 10468-10472.
DOI: 10.1002/chem.201301281

Abstract: Stimulating stuff: The synthesis and optical activities of several metal oxide nanoparticles introduced in the helical pores of chiral mesoporous silica supports are reported (see figure). Both coloured and colourless metal oxides exhibited the Cotton effect at their characteristic absorption bands, attributed to electronic transitions from the ground state to excited states under an asymmetric electric field
Author keywords: chirality, circular dichroism, mesoporous materials, metal oxides, optical activity


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