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Reference type: Journal
Authors: Shamsipur M, Rajabi HR, Pourmortazavi SM, Roushani M
Article Title: Ion imprinted polymeric nanoparticles for selective separation and sensitive determination of zinc ions in different matrices.
Publication date: 2014
Journal: Spectrochimica Acta Part A-Molecular and Biomolecular Spctroscopy
Volume: 117
Page numbers: 24-33.
DOI: 10.1016/j.saa.2013.07.094
Alternative URL: http://www.sciencedirect.com/science/article/pii/S1386142513008421

Abstract: Preparation of Zn2+ ion-imprinted polymer (Zn-IIP) nanoparticles is presented in this report. The Zn-IIP nanoparticles are prepared by dissolving stoichiometric amounts of zinc nitrate and selected chelating ligand, 3,5,7,20,40-pentahydroxyflavone, in 15 mL ethanol-acetonitrile (2:1; v/v) mixture as a porogen solvent in the presence of ethylene glycol-dimethacrylate (EGDMA) as cross-linking, methacrylic acid (MAA) as functional monomer, and 2,2-azobisisobutyronitrile (AIBN) as initiator. After polymerization, Cavities in the polymer particles corresponding to the Zn2+ ions were created by leaching the polymer in HCl aqueous solution. The synthesized IIPs were characterized by scanning electron microscopy, X-ray diffraction, Fourier transform infrared spectroscopy, fluorescence spectroscopy and thermal analysis techniques. Also, the pH range for rebinding of Zn2+ ion on the IIP and equilibrium binding time were optimized, using flame atomic absorption spectrometry. In selectivity study, it was found that imprinting results increased affinity of the material toward Zn2+ ion over other competitor metal ions with the same charge and close ionic radius. The prepared IIPs were repeatedly used and regenerated for six times without any significant decrease in polymer binding affinities. Finally, the prepared sorbent was successfully applied to the selective recognition and determination of zinc ion in different real samples
Template and target information: zinc ion, Zn(II)
Author keywords: Ion imprinted polymers, nanoparticles, characterization, Zinc ion, Flame atomic absorption spectroscopy, separation


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