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Reference type: Journal
Authors: Liu XL, Lv P, Yao GX, Ma CC, Tang YF, Wu YT, Huo PW, Pan JM, Shi WD, Yan YS
Article Title: Selective degradation of ciprofloxacin with modified NaCl/TiO2 photocatalyst by surface molecular imprinted technology.
Publication date: 2014
Journal: Colloids and Surfaces A: Physicochemical and Engineering Aspects
Volume: 441
Page numbers: 420-426.
DOI: 10.1016/j.colsurfa.2013.10.005
Alternative URL: http://www.sciencedirect.com/science/article/pii/S0927775713007590

Abstract: The modified NaCl/TiO2 photocatalyst of selected degradation was synthesized by surface molecular imprinted technology with ciprofloxacin (CIP) as the molecular template. The acrylamide (AM), trimethylolpropane acrylate (TMPTA), and 2,2-azobisisobutyronitrile (AIBN) were considered to be functional monomer, cross-linking and initiate reagents, respectively. The as-prepared photocatalysts were characterized by X-ray diffraction (XRD), UV-vis diffuse reflectance spectra (UV-vis DRS), transmission electron microscopy (TEM), scanning electron microscopy (SEM), thermal gravimetry (TG) and Fourier transform infrared (FT-IR). Compared with the non-imprinted photocatalyst, the molecular imprinted photocatalyst exhibits higher selectivity and photo-degradation capacity for CIP. The degradation ratio of CIP could reach 70.90% in 60 min under visible irradiation. The selectivity of the MIP photoctalyst enhanced the photocatalytic activity to CIP
Template and target information: ciprofloxacin, CIP
Author keywords: selectivity, Photo-degradation, Ciprofloxacin, NaCl, TiO2, surface molecular imprinting


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