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Reference type: Journal
Authors: Shin MJ, Shin YY, Shin JS
Article Title: Sensing capability of molecularly imprinted self-assembled monolayer fabricated using dithiol compound.
Publication date: 2014
Journal: Journal of Industrial and Engineering Chemistry
Volume: 20
Issue: (1)
Page numbers: 91-95.
DOI: 10.1016/j.jiec.2013.04.022
Alternative URL: http://www.sciencedirect.com/science/article/pii/S1226086X13001706

Abstract: Synthesis of 3,5-di(6-mercaptohexyloxy)toluene (DMHT) was achieved starting from orcinol. A molecularly imprinted self-assembled monolayer (SAM) was fabricated by forming an SAM with both DMHT and the template molecule (cholesterol), followed by removal of the template molecules by solvent extraction. These imprinted SAMs were capable of discriminating the imprinted substrate. The stability of the imprinted SAMs was estimated precisely using a quartz crystal microbalance. In comparison to the results used monothiol compounds, the duration of the sensing capability of this imprinted SAM was improved greatly. The two thiol functional groups in DMHT clearly had a significant effect on the duration
Template and target information: cholesterol
Author keywords: molecular imprinting, self-assembled monolayer, Dithiol compound, Cyclic voltammogram, cholesterol, sensor


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