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Reference type: Journal
Authors: Lulinski P, Dana M, Maciejewska D
Article Title: Synthesis and characterization of 4-(2-aminoethyl)aniline imprinted polymer as a highly effective sorbent of dopamine.
Publication date: 2014
Journal: Talanta
Volume: 119
Page numbers: 623-631.
DOI: 10.1016/j.talanta.2013.11.060
Alternative URL: http://www.sciencedirect.com/science/article/pii/S003991401300948X

Abstract: The aim of the study was to develop an efficient sorbent for the separation of dopamine. 4-(2-Aminoethyl)aniline was chosen as a pseudo-template to produce the imprinted polymers from seven different functional monomers in the presence of ethylene glycol dimethacrylate as a cross-linker. The binding capacity showed that the highest binding specificity towards dopamine was achieved when methacrylic acid was used as the monomer in methanol solution to form a polymer matrix. The imprinting factor value was equal to 22.96. Other biogenic amines were bound much more weakly. A simple theoretical model was used to give an insight into the imprinting process and the selectivity of polymer matrix. Two artificial urine samples were used as the complex matrices to show the usefulness of the new sorbent for bioanalysis
Template and target information: 4-(2-Aminoethyl)aniline, pseudo-template, dopamine
Author keywords: Molecularly imprinted polymers, dopamine, 4-(2-Aminoethyl)aniline, molecular modeling, Binding properties


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