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Reference type: Journal
Authors: Belokon YN, Tararov VI, Saveleva TF, Vorobev MM, Vitt SV, Sizoy VF, Sukhacheva NA, Vasilev GV, Belikov VM
Article Title: Memory of a polymeric matrix, stabilizing the initial conformation of potassium bis[N-(5-methacryloylamino)-salicylidene-(S)-norvalinato]-cobaltate(III) in the deuterium-exchange.
Publication date: 1983
Journal: Makromolekulare Chemie-Macromolecular Chemistry And Physics
Volume: 184
Issue: (11)
Page numbers: 2213-2223.
DOI: 10.1002/macp.1983.021841103

Abstract: Copolymerization of potassium - and -bis[N-(5-methacryloylamino)salicylidene-(S)-norvalinato]-cobaltate(III) (1 and 2) with acrylamide and N,N-methylenediacrylamide gives crosslinked gels. The behaviour of the amino acid moiety in the gel obtained from the isomer with the (S,S) configuration does not differ from that of the monomeric model compound 4. The (S,S) isomer gives gels, in which a part of the complex proves to be attached by both phenyl moieties to one polymeric chain forming a macrocycle. Deuterium exchange in such complexes proceeds with full retention of the configuration of the amino acid


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