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Reference type: Journal
Authors: Bakas I, Salmi Z, Jouini M, Geneste F, Mazerie I, Floner D, Carbonnier B, Yagci Y, Chehimi MM
Article Title: Picomolar Detection of Melamine Using Molecularly Imprinted Polymer-Based Electrochemical Sensors Prepared by UV-Graft Photopolymerization.
Publication date: 2015
Journal: Electroanalysis
Volume: 27
Issue: (2)
Page numbers: 429-439.
DOI: 10.1002/elan.201400382

Abstract: Molecularly imprinted polymer (MIP) films of melamine were prepared by photopolymerization of vinylic monomers on diazonium-modified gold electrodes. The gold-grafted MIPs are specific and selective for melamine in either organic or aqueous media. The interferent molecules cyromazine and cyanuric acid were not recognized by the MIPs. The limit of detection was as low as 1.75 x 10-12 mol L-1 at S/N=3. Efficiency of melamine rebinding is related to the solubility parameter of the organic solvent or pH and ionic strength of the aqueous medium. It is concluded that diazonium salts permit to design robust electrochemical MIP sensors
Template and target information: melamine
Author keywords: diazonium salts, Molecularly imprinted polymers, Melamine, solvent effect, electrochemical sensors

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