MIPs logo MIPdatabase      GSSMIP 2019; Deadline for abstract submission: 30th June 2019; Registration deadline: 19th July 2019
Custom Search
Reference type: Journal
Authors: Yola ML, Atar N, Eren T, Karimi-Maleh H, Wang SB
Article Title: Sensitive and selective determination of aqueous triclosan based on gold nanoparticles on polyoxometalate/reduced graphene oxide nanohybrid.
Publication date: 2015
Journal: RSC Advances
Volume: 5
Issue: (81)
Page numbers: 65953-65962.
DOI: 10.1039/C5RA07443F

Abstract: The widespread use of triclosan (TCS) in household cleaning products, medical devices and personal care poses a potential risk to the ecological system and human health due to its release into sediments, surface water and ground water resources and chronicle toxicity to aquatic organisms. A novel molecular-imprinted electrochemical sensor based on gold nanoparticles decorating polyoxometalate (H3PW12O40)/reduced graphene oxide was developed for determination of trace TCS in wastewater. Reduced graphene oxide (rGO) was functionalized by polyoxometalate (POM) through electrostatic interaction between the POM and rGO nanosheets to produce a photocatalyst (POM/rGO) in aqueous solution. Gold nanoparticles (AuNPs) were further deposited on the POM/rGO without using any reducing agent and the prepared nanomaterial (AuNPs/POM/rGO) was employed to modify a glass carbon (GC) electrode (AuNPs/POM/rGO/GC) under infrared light. Several techniques, X-ray photoelectron spectroscopy (XPS), reflection-absorption infrared spectroscopy (RAIRS), scanning electron microscopy (SEM), and transmission electron microscopy (TEM), were used for electrode characterization. TCS imprinted film was generated on AuNPs/POM/rGO/GC via polymerization of phenol and TCS and characterized by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The sensor was found to have a linear detection range and a limit of TCS at 0.5-50.0 nM and 0.15 nM, respectively. The molecular imprinted sensor was applied to wastewater and lakewater samples and demonstrated effective performance as compared to other complicated methods
Template and target information: triclosan, TCS


  Template of Doom spoof movie poster shirt  Chemistry peptide mug  Chemists are fun customisable shirt

Molecules Special Issue call      Appeal for information






 

Join the Society for Molecular Imprinting
Logo of the Society for Molecular Imprinting

New items RSS feed
new items RSS feed  View latest updates

Sign-up for e-mail updates:
Choose between receiving an occasional newsletter or more frequent e-mail alerts.
Click here to go to the sign-up page.


Is your name elemental or peptidic? Enter your name and find out by clicking either of the buttons below!
Other products you may like:
view listings for MIP books on eBay:



Mickey Mouse 90th Anniversary banner