MIPs logo MIPdatabase      MIP2018 Conference website
Custom Search
Reference type: Journal
Authors: Ktari N, Fourati N, Zerrouki C, Ruan M, Seydou M, Barbaut F, Nal F, Yaakoubi N, Chehimi MM, Kalfat R
Article Title: Design of a polypyrrole MIP-SAW sensor for selective detection of flumequine in aqueous media. Correlation between experimental results and DFT calculations.
Publication date: 2015
Journal: RSC Advances
Volume: 5
Issue: (108)
Page numbers: 88666-88674.
DOI: 10.1039/C5RA16237H

Abstract: A shear horizontal surface acoustic wave sensor (SH-SAW) operating at 104 MHz was functionalized with a polypyrrole (PPy) molecularly imprinted polymer (MIP) for selective detection of flumequine (FLU) in aqueous media. In order to prevent the formation of FLU complexes with the gold sensing area of the SH-SAW sensor, a thin blocking polypyrrole layer was deposited by chronoamperometry before the MIP electrochemical deposition. The detection limit of the designed sensor was of the order of 1 μM and the sensitivity was estimated to be at 9.36 0.39 mM-1. Selectivity tests were made with levofloxacin (LEVO), an interfering fluoroquinolone antibiotic. Results indicate that the designed PPy-MIP recognition layer is selective of flumequine. Quantum chemical calculations, based on density functional theory (DFT), have permitted us to highlight the importance of the PPy blocking layer, on the one hand, and the nature of interactions between the polypyrrole matrix and FLU and LEVO analytes, on the other hand
Template and target information: flumequine, FLU


  I love MISPE bag  multi MIPs logo mug  American periodic table patriotic shirt

Molecules Special Issue call






Join the Society for Molecular Imprinting
Logo of the Society for Molecular Imprinting

New items RSS feed
new items RSS feed  View latest updates

Sign-up for e-mail updates:
Choose between receiving an occasional newsletter or more frequent e-mail alerts.
Click here to go to the sign-up page.


Is your name elemental or peptidic? Enter your name and find out by clicking either of the buttons below!
Other products you may like:
view listings for MIP books on eBay:
US listings   UK listings

Searching for Molecular Imprinting books on Amazon.com:
Molecular Imprinting
Imprinted Polymers
Polymer Chemistry
Organic Chemistry
Biosensors

Find what you need at Amazon.com

Lab supplies from Amazon