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Reference type: Journal
Authors: Han Y, Nowak P, Colomb-Delsuc M, Leal MP, Otto S
Article Title: Instructable Nanoparticles Using Dynamic Combinatorial Chemistry.
Publication date: 2015
Journal: Langmuir
Volume: 31
Issue: (46)
Page numbers: 12658-12663.
DOI: 10.1021/acs.langmuir.5b03673

Abstract: The application of nanoparticles to the multivalent recognition of biomacromolecules or programmed self-assembly requires control over the relative placement of chemical groups on their surface. We have developed a method to direct the functionalization of surfaces of aldehyde-equipped gold nanoparticles using a DNA template. An error-correction mechanism is built into the functionalization process thanks to the thermodynamic control enabled by the hydrazone exchange reaction. This reversible reaction can be conveniently switched off by removing the catalyst, preserving the functionalization
Template and target information: DNA

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