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Reference type: Journal
Authors: Ndunda EN, Madadi VO, Mizaikoff B
Article Title: An alternative clean-up column for the determination of polychlorinated biphenyls in solid matrices.
Publication date: 2015
Journal: Environmental Science: Processes & Impacts
Volume: 17
Issue: (12)
Page numbers: 2101-2109.
DOI: 10.1039/C5EM00409H
Alternative URL: https://www.researchgate.net/publication/283278595_An_alternative_clean-up_column_for_the_determination_of_polychlorinated_biphenyls_in_solid_matrices

Abstract: The need for continuous monitoring of polychlorinated biphenyls (PCBs) has necessitated the development of analytical techniques that are sensitive and selective with minimal reagent requirement. In light of this, we developed a column for clean-up of soil and sediment extracts, which is less demanding in terms of the amount of solvent and sorbent. The dual-layer column consists of acidified silica gel and molecularly imprinted polymers (MIPs). MIPs were synthesized via aqueous suspension polymerization using PCB 15 as the dummy template, 4-vinylpyridine as the functional monomer and ethylene glycol dimethacrylate as the cross-linker and the obtained particles characterized via SEM, BET, and batch rebinding assays. Pre-concentration of the spiked real-world water sample using MISPE gave recoveries between 85.2 and 104.4% (RSD < 8.69). On the other hand, the specific dual-layer column designed for clean-up of extracts from complex matrices provided recoveries of 91.6-102.5% (RSD < 4%) for spiked soil, which was comparable to clean-up using acidified silica (70.4-90.5%; RSD < 3.72%) and sulfoxide modified silica (89.7-103.0%; RSD < 13.0%). However, the polymers were reusable maintaining recoveries of 79.8-111.8% after 30 cycles of regeneration and re-use, thereby availing a cost-effective clean-up procedure for continuous monitoring of PCBs. Method detection limits were 0.01-0.08 ng g-1 and 0.002-0.01 ng mL-1 for solid matrices and water, respectively
Template and target information: dummy template, PCB 15, polychlorinated biphenyls


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