Authors: Tsukagoshi K
, Kawasaki R
, Maeda M
, Takagi M
Preparation and sugar binding property of microspheres having surface-anchored phenylboronic acid groups.
Publication date: 1994
Journal: Chemistry Letters
Abstract: Microspheres having phenylboronic acid groups on the resin surface were successfully prepared by emulsion polymerization of styrene, butyl acrylate, and m-acrylamidophenylboronic acid. The microspheres were swollen in an alkaline aqueous suspension by adding methylethylketone so that phenylboronic acid groups in the resin migrate out to the aqueous-organic interface in their ionized forms. D-Glucose was bound onto the microsphere by complex (ester) formation between phenylboronic acid moiety and cis-diol group of D-Glucose
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