Authors: Gaeta M
, Oliveri IP
, Fragala ME
, Failla S
, D'urso A
, Di Bella S
, Purrello R
Chirality of self-assembled achiral porphyrins induced by chiral Zn(II) Schiff-base complexes and maintained after spontaneous dissociation of the templates: a new case of chiral memory.
Publication date: 2016
Journal: Chemical Communications
Abstract: Herein, we exploit the induction of chirality by chiral Zn(II) Schiff-base complexes, followed by their spontaneous dissociation in aqueous solution, providing for the first time a possibility of overcoming the template removal steps, to demonstrate memorization of chirality in porphyrin hetero-aggregates
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