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Reference type: Journal
Authors: Wolska J
Article Title: Thermoresponsive molecularly imprinted polymer for rapid sorption and desorption of diethyl phthalate.
Publication date: 2016
Journal: Separation Science and Technology
Volume: 51
Issue: (15-16)
Page numbers: 2547-2553.
DOI: 10.1080/01496395.2016.1165706

Abstract: A thermoresponsive molecularly imprinted polymer (T-MIP) for removal of diethyl phthalate (DEP) was obtained. The polymer was synthesized using N-isopropylacrylamide (NIPAM), methyl methacrylate (MMA) and ethylene glycol dimethacrylate (EGDMA). The studies have been focused on a selection of monomers composition and kind of solvent. The ability of molecular recognition towards DEP was evaluated. The obtained MIPs showed temperature-sensitive sorption comparing to non-imprinted analogues. The greatest affinity towards template was observed at 35-�C for sorbent prepared from NIPAM:MMA of 3:7 ratio, with the 60% of crosslinker and toluene as a solvent. The best conditions for DEP desorption were noted at 60 �C
Template and target information: diethyl phthalate, DEP
Author keywords: Thermoresponsive molecularly imprinted polymers, diethyl phthalate, sorption, desorption,

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