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Reference type: Journal
Authors: Mitreva M, Dakova I, Yordanova T, Karadjova I
Article Title: Chromate surface-imprinted silica gel sorbent for speciation of Cr in surface waters.
Publication date: 2016
Journal: Turkish Journal of Chemistry
Volume: 40
Issue: (6)
Page numbers: 921-932.
Alternative URL: http://journals.tubitak.gov.tr/chem/abstract.htm?id=19785

Abstract: This study is focused on the synthesis of chromate anion imprinted sorbent supported on silica gel for non-chromatographic Cr speciation in surface waters. The preparation procedure is based on grafting of 3-methyl-1-trimethoxysilylpropylimidazolium, preliminarily coordinated to CrO4 2- as a template ion, onto the surface of silica gel. Sorption and desorption characteristics of surface-imprinted sorbent toward Cr(III) and Cr(VI) were examined by batch solid-phase extraction. An excellent separation of Cr(VI), selectively retained on the sorbent, from Cr(III) remained in the solution, was achieved at pH 2 - 3 for 20 min. A freshly prepared mixture of ascorbic acid and nitric acid was selected as the most efficient eluent for quantitative desorption of the retained Cr(VI). An analytical procedure for Cr speciation in surface waters was developed and validated through analysis of certified reference materials. Detection limits achieved and relative standard deviations for typical concentration levels of Cr(VI) in surface waters matched the requirements of analytical procedures used in monitoring programs.
Template and target information: chromate ion, Cr(VI)
Author keywords: Chromate anion surface-imprinted sorbent, Chromium speciation, Solid-phase extraction, surface waters


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