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Reference type: Journal
Authors: Yusoff MM, Mostapa NRN, Sarkar MS, Biswas TK, Rahman ML, Arshad SE, Sarjadi MS, Kulkarni AD
Article Title: Synthesis of ion imprinted polymers for selective recognition and separation of rare earth metals.
Publication date: 2017
Journal: Journal of Rare Earths
Volume: 35
Issue: (2)
Page numbers: 177-186.
DOI: 10.1016/S1002-0721(17)60897-4
Alternative URL: http://www.sciencedirect.com/science/article/pii/S1002072117608974

Abstract: Lanthanide-ion imprinted polymers (L-IIPs) were synthesized by stoichiometric amounts of rare earth ions and the cavities in the polymers were created for the corresponding lanthanide ions. The maximum sorption capacities were estimated to be 125.3, 126.5, 127.6, 128.2 and 129.1 mg/g for Pr, Nd, Sm, Eu and Gd, respectively at pH 6. In the selectivity study, the L-IIPs exhibited good selectivity to the specific rare earth ions in the presence of coexisting cations. The imprinting results were found to be excellent with some rare earth ions over other competitor rare earth ions with the same charges and close ionic radius
Template and target information: lanthanide ions, Pr(III), Nd(III), Sm(III), Eu(III)Gd(III)
Author keywords: Ion-imprinted polymers, rare earths, separation, adsorption, lanthanide-ions

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