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Reference type: Journal
Authors: Li XJ, Jiao HF, Shi XZ, Sun AL, Wang XJ, Chai JY, Li DX, Chen J
Article Title: Development and application of a novel fluorescent nanosensor based on FeSe quantum dots embedded silica molecularly imprinted polymer for the rapid optosensing of cyfluthrin.
Publication date: 2018
Journal: Biosensors and Bioelectronics
Volume: 99
Page numbers: 268-273.
DOI: 10.1016/j.bios.2017.07.071
Alternative URL: http://www.sciencedirect.com/science/article/pii/S0956566317305286

Abstract: A novel molecularly imprinted silica layer appended to FeSe quantum dots (MIP-FeSe-QDs) was fabricated and utilized as a recognition element to develop a selective and sensitive fluorescent nanosensor for cyfluthrin (CYF) determination. The MIP-FeSe-QDs were characterized by fluorescence spectrometry, scanning electron microscopy, transmission electron microscopy, and Fourier transform infrared spectroscopy. Excellent selectivity and high sensitivity of MIP-FeSe-QDs to CYF molecules were observed based on the fluorescence quenching of FeSe-QDs. Under optimal conditions, a good linear relationship was found between fluorescence quenching effect and increased CYF concentration within 0.010-0.20 mg/L, with a correlation coefficient of 0.9911. The practicality of the developed sensor method for CYF detection in fish and sediment samples was further validated. Good recoveries ranging from 88.0% to 113.9% with <6.8% relative standard deviations were obtained. The detection limits of CYF in sediment and fish samples were 1.3 and 1.0 μg/kg, respectively. This study established a novel, rapid fluorescent nanosensor detection method based on MIP-QDs for successfully analyzing CYF in fish and sediment samples
Template and target information: cyfluthrin, CYF
Author keywords: FeSe quantum dot, molecularly imprinted, Cyfluthrin, determination


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