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Reference type: Journal
Authors: Yola ML, Göde C, Atar N
Article Title: Molecular imprinting polymer with polyoxometalate/carbon nitride nanotubes for electrochemical recognition of bilirubin.
Publication date: 2017
Journal: Electrochimica Acta
Volume: 246
Page numbers: 135-140.
DOI: 10.1016/j.electacta.2017.06.053
Alternative URL: http://www.sciencedirect.com/science/article/pii/S0013468617312926

Abstract: In this work, a new molecular imprinted sensor based on polyoxometalate (H3PW12O40, POM) functionalized carbon nitride nanotubes (C3N4 NTs) nanocomposite was prepared for bilirubin (BR) analysis. The structures of prepared surfaces based on the nanocomposite were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), x-ray photoelectron spectroscopy (XPS) and energy dispersive x-ray analysis (EDX). After that, BR imprinted electrode on H3PW12O40/C3N4 NTs nanocomposite was developed by cyclic voltammetry (CV) in 100mM pyrrole containing 25mM BR. The linearity range and the detection limit of the developed method were calculated as 1.0 x 10-12 - 1.0 x 10-10 M and 3.0 x 10-13 M, respectively. In addition, the imprinted sensor was applied to human plasma samples with high recovery and selectivity
Template and target information: bilirubin
Author keywords: Bilirubin, Polyoxometalate, Carbon nitride nanotubes, molecular imprinting


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