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Reference type: Journal
Authors: Zheng XM, Xu TG, Shi R, Lu N, Zhang J, Jiang CY, Zhang C, Zhou J
Article Title: Preparation of hollow porous molecularly imprinted polymers for N-nitrosamine adsorption.
Publication date: 2018
Journal: Materials Letters
Volume: 211
Page numbers: 21-23.
DOI: 10.1016/j.matlet.2017.09.047
Alternative URL: http://www.sciencedirect.com/science/article/pii/S0167577X17313836

Abstract: Novel hollow molecularly imprinted polymer (HMIPs) microspheres were synthesized via two-stage dispersion polymerization and swelling seed polymerization technique with nicotinamide (NAM) as the template molecule. Binding experiments showed that the HMIPs possessed excellent binding properties toward N-nitroamines, including fast mass transfer rate, and efficient adsorption performance with the adsorption capacity reaching up to 1.7 mg/g, which was 3 times higher than that of hollow non-imprinted polymers (HNIPs). The fast binding kinetics for one N-nitrosamine (4-(methylnitrosamino)-1-(3-pyridine)-1-butanone, NNK) was attributed to the hollow porous structure with the imprinted cavities on both external and internal surface of the HMIPs
Template and target information: nicotinamide, NAM
Author keywords: porous materials, polymers, adsorption, Swelling seed polymerization, Nitrosamines

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