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Reference type: Journal
Authors: Kim JH, Byeon M, Jeong YC, Oh JY, Jung Y, Fechler N, Yang SJ, Park CR
Article Title: Morphochemical imprinting of melamine cyanurate mesocrystals in glucose-derived carbon for high performance lithium ion batteries.
Publication date: 2017
Journal: Journal of Materials Chemistry A
Volume: 5
Issue: (39)
Page numbers: 20635-20642.
DOI: 10.1039/C7TA05853E

Abstract: A novel dual imprinting method is suggested to synthesize pyridinic N-enriched, hierarchically porous carbon. Rose-like melamine cyanurate (MCA) mesocrystals are prepared by simple self-assembly and utilized as a sacrificial template. The unique morphological and chemical features of the MCA are imprinted in the carbon source during carbonization. Curled graphene-like layers with a high nitrogen content (19.9 at%, especially 8.9 at% of pyridinic N) are interconnected to form a unique red blood cell-shaped morphology with a hierarchical pore structure. The resulting material exhibits an outstanding electrochemical performance (2019 mA h g-1 at 100 mA g-1 and 643 mA h g-1 at 2000 mA g-1 after 250 cycles) when evaluated as an anode material for lithium ion batteries. Furthermore, this novel imprinting strategy can provide a simple and efficient methodology to produce pyridinic N-enriched, hierarchically porous carbonaceous materials for extensive applications
Template and target information: melamine cyanurate, MCA


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