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Reference type: Journal
Authors: Akbulut-Söylemez M, Barsbay M, Güven O
Article Title: Preparation of well-defined erythromycin imprinted non-woven fabrics via radiation-induced RAFT-mediated grafting.
Publication date: 2018
Journal: Radiation Physics and Chemistry
Volume: 142
Page numbers: 77-81.
DOI: 10.1016/j.radphyschem.2017.01.041
Alternative URL: http://www.sciencedirect.com/science/article/pii/S0969806X16306132

Abstract: Radiation-induced RAFT polymerization technique was applied to synthesize well-defined molecularly imprinted polymers (MIPs) of erythromycin (ERY). Methacrylic acid (MAA) was grafted onto porous polyethylene (PE)/polypropylene (PP) nonwoven fabrics, under γ-irradiation by employing 2-pheny-2-propyl benzodithioate as the RAFT agent and ethylene glycol dimethacrylate (EGDMA) as the crosslinker. MAA/erythromycin ratios of 2/1, 4/1, 6/1 were tested to optimize the synthesis of MIPs. The highest binding capacity was encountered at a MAA/ERY ratio of 4/1. Non-imprinted polymers (NIPs) were also synthesized in the absence of ERY. The MIPs synthesized by RAFT method presented a better binding capacity compared to those prepared by conventional method where no RAFT agent was employed
Template and target information: erythromycin, ERY
Author keywords: Molecularly imprinted polymers, Radiation induced grafting, RAFT polymerization, Erythromycin

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