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Reference type: Journal
Authors: Khan S, Hussain S, Wong A, Foguel MV, Gonçalves LM, Pividori Gurgo MI, Sotomayor M
Article Title: Synthesis and characterization of magnetic-molecularly imprinted polymers for the HPLC-UV analysis of ametryn.
Publication date: 2018
Journal: Reactive and Functional Polymers
Volume: 122
Page numbers: 175-182.
DOI: 10.1016/j.reactfunctpolym.2017.11.002
Alternative URL: https://www.researchgate.net/publication/320925874_Synthesis_and_characterization_of_magnetic-molecularly_imprinted_polymers_for_the_HPLC-UV_analysis_of_ametryn

Abstract: Magnetic molecularly imprinted polymer (mag-MIP) were developed for the analysis of ametryn (4-N-ethyl-6-methylsulfanyl-2-N-propan-2-yl-1,3,5-triazine-2,4-diamine), a popular triazine herbicide. Iron oxide (Fe3O4) nanoparticles were synthetized, and then modified with tetraethoxysilane (TEOS) and 3-mercaptopropyltrimethoxysilane (MPS). Then MIPs' polymerimerization occurred in the nanoparticles' surface, using ethylene-glycol-dimethacrylate (EGDMA) as the building monomer, 2,2'-azobis(2-methylpropionitrile) (AIBN) as the radical initiator, and 2-vinylpyridine as the functional monomer. The functional monomer was previously chosen by computational simulation. The mag-MIPs' adsorption behavior well-fitted a Langmuir model (qm of 8.6 mg g-1, KL of 5.2 L mg-1) and pseudo first order kinetics (k1 of 2.5 x 10-4 s-1). The developed analytical methodology, using high-performance liquid chromatography with UV detection (HPLC-UV), showed suitable selectivity and had a limit of detection (LOD) and quantification (LOQ) of 25 and 82 nmol L-1, respectively
Template and target information: ametryn, 4-N-ethyl-6-methylsulfanyl-2-N-propan-2-yl-1,3,5-triazine-2,4-diamine
Author keywords: analytical chemistry, environmental analysis, food analysis, Food quality, pesticide

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