Authors: Zhang HQ
, Verboom W
, Reinhoudt DN
9-(Guanidinomethyl)-10-vinylanthracene: a suitable fluorescent monomer for MIPs.
Publication date: 2001
Journal: Tetrahedron Letters
Abstract: 9-(Guanidinomethyl)anthracene derivatives with a bromo (6) or a vinyl group (10) at the 10-position have been prepared starting from 9-bromoanthracene (1). They show 1:1 complexation with carboxylic acids or carboxylates with K-values of 1.2-1.4 x 10(5) M-1 in deuteriomethanol. Copolymerization of 9- vinylanthracene, 9-(guanidinomethyl)-10-vinylanthracene hydrochloride (10), and the 1:1 complex of 10 and ammonium benzoate with ethyleneglycol dimethacrylate (EDMA) gave the polymers in 77-92% yield. (C) 2001 Elsevier Science Ltd. All rights reserved
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